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When liquid and gas phases are both present in an equilibrium mixture of reacting species, Eq (1 144), a criterion of vaporlliquid equilibrium, must be satisfied along with the equation of chemical-reaction equilibrium Consider, for example, the reaction of gas A with liquid water B to form an aqueous solution C Several choices in the method of treatment exist The reaction may be assumed to occur entirely in the gas phase with simultaneous transfer of material between phases to maintain phase equilibrium In this case, the equilibrium constant is evaluated from AGO data based on standard states for the species as gases, ie, the ideal-gas states at 1 bar and the reaction temperature On the other hand, the reaction may be assumed to occur in the liquid phase, in which case AGO is based on standard states for the species as liquids Alternatively, the reaction may be written:

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in which case the AGO value is for mixed standard states: C as a solute in an ideal 1-molal aqueous solution, B as a pure liquid at 1 bar, and A as a pure ideal gas at 1 bar For this choice of standard states, the equilibrium constant as given by Eq (1310) becomes:

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The second term a-ises from Eq (1335) applied to species C, Eq (1329) applied to B with f s / f j = 1, and the fact that f" = P " for species A in the gas phase Since K depends on , the standard states, this value of K is not the same as that obtained when, for example, the standard state for each species is chosen as the ideal-gas state at 1 bar However, all methods theoretically lead to the same equilibrium composition, provided Henry's law as applied to species C in solution is valid In practice, a particular choice of standard states may simplify calculations or yield more accurate results, because it makes better use of the available data The nature of the calculations required for heterogeneous reactions is illustrated in the following example

The first mailbox is called Mailbox 1; the second mailbox is called Mailbox 2, and so on If you look at the configuration panel for the SEND MESSAGE block, you ll see that the last section is called Mailbox, and it contains a drop-down menu Select this drop-down menu, and you ll see that you can select from numbers 1 to 10 It s simple! When you place a Text, Number, or Logic value in Mailbox 3, for example, that value is held in that mailbox (remember, a Text value can be a single character or multiple characters but is still considered a single value to a mailbox) Up to five values can be held per mailbox, but the values held must be of the same type (Text, Number, or Logic).

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